Structure and reactivity of bicyclic methylene aziridines prepared by intramolecular aziridination of allenes.
نویسندگان
چکیده
Unprecedented bicyclic methylene aziridines are prepared by rhodium(II)-catalyzed allene aziridination of buta-2,3-dienyl carbamates. Aspects of their NMR and X-ray data are described and a preliminary reactivity profile is given, including overall S(N)V-mode ring-opening with organometallic reagents.
منابع مشابه
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 8 13 شماره
صفحات -
تاریخ انتشار 2010